30.08.2011 -
By Michele Scozzai
André Gide, French winner of the Nobel Prize
for Literature in 1947, declared that there are no problems "only
solutions". That thought, or at least hope, must have passed
through the mind of the young restorer from Trieste, who in the
spirit of innovation knocked on AREA's door in 2007 to stubbornly
challenge conventions. An expert in wood renovation- with passion,
insight and flair - the craftsman presented AREA staff with the
'problem-no-problem' which haunted his days.
Restoration is an almost surgical profession,
its practitioners turn back the clock on objects and works of art,
modern day Dorian Grays of inanimate beauty but who, as the
restorer recounted, have to work every day with solvents containing
methylene chloride (or dicloromethane), commonly known as
'universal' paint-remover.
Dicloromethane is an effective solvent which is
also widely used by the food industry for the decaffeination of
coffee. It is, however, toxic and though scientific proof is as yet
inconclusive, it is believed to be potentially carcinogenic.
Liquid, colourless and volatile, it has to be disposed of according
to strict regulations and its users must take adequate safety
precautions: wearing masks, gloves, overalls and goggles. There is
no escape for restorers: universal paint-stripper works and all
attempts to imitate it using less harmful solvents have had little
success.
The AREA staff initiated a sector study and as
a first step contacted a sample group of restorers in Friuli
Venezia Giulia to get an understanding of how common, and pressing,
a concern this was. A female restorer who had recently married
admitted that she had recently given up the profession, a lifelong
passion, because of her fears about the effects of paint-removers
on a future possible pregnancy.
Professor Gianpiero Adami of the Chemical
Sciences Department at the University of Trieste was chosen to set
up an investigation and to find a solution. Adami has specific
experience in environmental chemistry and has worked for some time
with the Regional Centre for Cataloguing and Restoration of
Cultural Heritage based at Villa Manin di Passariano (Udine),
founded in 1971 and considered to be one of the leading national
organisations working in the field.
Once an analysis of the current situation had
been carried out, AREA studied the national and international
standards regarding the use of paint-removers and similar
substances, and searched patent and document records to see if
there was an environmentally-friendly alternative to universal
paint-stripper. With the collaboration of Adami, tens of companies
working in the sector were contacted and, with the help of a group
of restorers, the main competitors to dicloromethane available on
the market were put to the test.
Performance, hazards, composition, applications
and reaction time were all evaluated. The research study found that
while there are numerous 'green', non-toxic products available,
none of them were fully successful in meeting the needs of the
restorers. Some penetrated too deeply and risked damaging surfaces,
others didn't penetrate enough, and others which seemed to work
well were not cost efficient. It seemed that there was no middle
way- a product with the same level of performance as universal
paint-remover but without the risks that it poses to health and the
environment, and without the need for specialised waste
disposal.
Once the first phase of monitoring was
complete, Adami began to experiment with different chemical
compositions. After tens of different attempts and months of work.
He came up with a solution to prove Gide's rule.
The product conceived by Adami is a mixture of
two organic compounds, dimethyl sulfide and Iimonene, both solvents
with low toxicity. The former, discovered in 1867, is used in the
most diverse of fields, from the electronics industry to medicine.
The latter is a terpene found in citrus fruits, has a pleasant
odour, is a degreaser and, of course, takes its name from lemons,
it is used in cosmetics, botanics and other industries.
The real innovation in Gianpiero Adami's
product comes from combining the two substances to significantly
improve their efficacy. In spite of being slightly more costly than
dicloromethane paint-removers, the new product has produced
extremely encouraging results: it is efficient, has negliglibile
toxicity, needs no safety gear and is not considered hazardous
waste.
Adami, who says that some of his best ideas
come to him during the night or when travelling, didn't just stop
at creating a new product but has also created a new application
method. Unlike dicloromethane, the new paint-remover isn't applied
with a paintbrush and then removed with a scraper, but comes in gel
form which is spread on a strip of non-woven fabric and covered
with a protective layer of aluminium.
The strip is then placed onto the surface to be
treated and left to do its work. The solvent gradually passes to
the object (further increasing the effect of the compound) while
the protective layer prevents evaporation and limits inhalation by
the user. While the solvent is working the strip also absorbs any
residue, and the aluminium facilitates its use on uneven surfaces
such as corners, grooves or protusions.
An average application time of twenty to thirty
minutes gives excellent results and the use of incandescent lamp to
warm the area to be treated increases the potency of the solvent.
On more resistant paints and varnishes, such as those used on boats
or on parquet flooring, more than one application is generally
needed.
The product owes its existence to chance: a
protective glove was accidentally dropped onto one of the samples
which was being experimented on. The following morning, the
paint-remover and paint were perfectly attached to the surface of
the glove, just like in depilatory strips.
Once the formula had been finalised, AREA
created a strategy to protect the invention and today the product
is patented across Europe. Both the chemical compound and the
application method are protected. While Adami is the inventor, the
patent belongs, in accordance with national legislation, to the
University of Trieste.
The collaboration between Adami and AREA
continues: as the professor of Chemistry works to refine the
compound and evaluate new application methods, AREA is supporting
the production of a range of prototypes for use in other potential
fields: from restoration to ship building and from flooring to
building. The next goal, which is already being worked towards, is
turning the prototype into a real product.
At the moment nothing has been decided but the
most likely outcome is a partnership with a company working in this
sector. The first contacts have already been made. As Gide would
say, the solution is on its way.